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Course: Chemistry – 0570
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Chemistry – 0570

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1.2. Atomic Structure

Lesson Summary

Atoms are the smallest units of elements and consist of three subatomic particles: protons, neutrons and electrons. Protons and neutrons are located in the nucleus at the centre of the atom, while electrons move around the nucleus in energy levels called shells.

The atomic number represents the number of protons in the nucleus and identifies the element. The mass numberrepresents the total number of protons and neutrons in the nucleus. Atomic symbols are used to represent these values and help determine the number of neutrons in an atom.

Electrons are arranged in shells around the nucleus according to specific patterns. The electrons in the outermost shell are known as valence electrons and determine how atoms interact with other atoms. Atoms often gain, lose or share electrons in order to achieve a stable noble gas configuration.

Atoms of the same element can have different numbers of neutrons. These forms are known as isotopes. Examples include isotopes of hydrogen, carbon and chlorine.

Notes

1. Structure of an Atom

An atom is the smallest particle of an element that retains the chemical properties of that element.

Atoms consist of three main subatomic particles:

• Protons

Neutrons

Electrons

These particles are arranged in two main regions of the atom.

Nucleus

The nucleus is located at the centre of the atom and contains:

• protons

• neutrons

The nucleus contains most of the mass of the atom.

Electron Shells

Electrons move around the nucleus in energy levels called shells.

2. Charges and Relative Masses of Subatomic Particles

Particle

Charge

Relative Mass

Location

Proton

+1

1

Nucleus

Neutron

0

1

Nucleus

Electron

−1

1/1836

Electron shells

Key points:

• protons are positively charged

• electrons are negatively charged

• neutrons have no charge

Electrons have a much smaller mass compared with protons and neutrons.

3. Atomic Number (Proton Number)

The atomic number is the number of protons in the nucleus of an atom.

Atomic number determines:

• the identity of the element

• the number of electrons in a neutral atom

Example:

Carbon has atomic number 6

Therefore carbon contains:

6 protons

6 electrons

4. Mass Number (Nucleon Number)

The mass number is the total number of protons and neutrons in the nucleus.

Mass number = protons + neutrons

Example:

An atom with

6 protons

6 neutrons

Mass number = 12

5. Atomic Symbols

Atoms are represented using standard notation.

General format:

A

Z X

Where:

A = mass number

Z = atomic number

X = element symbol

Example:

¹²₆C

Mass number = 12

Atomic number = 6

Number of neutrons =

Mass number − atomic number

12 − 6 = 6 neutrons

6. Electron Arrangement in Shells

Electrons occupy shells around the nucleus.

For the first 20 elements:

First shell → maximum 2 electrons

Second shell → maximum 8 electrons

Third shell → maximum 8 electrons

Examples:

Hydrogen → 1

Helium → 2

Carbon → 2,4

Sodium → 2,8,1

Calcium → 2,8,8,2

This pattern is known as electron configuration.

7. Drawing Atomic Structures (Elements 1–20)

Atomic structure diagrams show:

• the nucleus containing protons and neutrons

• electrons arranged in shells

Example: Sodium

Protons = 11

Electrons = 11

Electron arrangement = 2,8,1

8. Valence Electrons and Noble Gas Configuration

Valence electrons are electrons in the outermost shell.

These electrons determine:

• chemical bonding

• chemical reactivity

Atoms tend to gain, lose or share electrons to achieve a stable noble gas configuration.

Noble gases have full outer shells.

Examples:

Helium → 2

Neon → 2,8

Argon → 2,8,8

Example:

Sodium (2,8,1) loses one electron to form 2,8, which is stable.

9. Isotopes

Isotopes are atoms of the same element with the same number of protons but different numbers of neutrons.

Therefore they have:

• same atomic number

• different mass numbers

Examples of Isotopes

Hydrogen Isotopes

Hydrogen-1 (Protium)

1 proton

0 neutrons

Hydrogen-2 (Deuterium)

1 proton

1 neutron

Hydrogen-3 (Tritium)

1 proton

2 neutrons

Carbon Isotopes

Carbon-12

Carbon-13

Carbon-14

All contain 6 protons but different neutron numbers.

Carbon-14 is used in radiocarbon dating.

Chlorine Isotopes

Chlorine-35

Chlorine-37

Both have 17 protons but different numbers of neutrons.